Contact Angle Measurements

Contact angle measurements are a technique for studying and measuring properties of the liquid — solid interface.  The wetting properties of a surface by a particular liquid can be characterized by measuring the contact angle of a small droplet of the liquid on the surface.  By using several liquids, the surface tension or surface energy of the surface to which they are applied can be determined.

The surface energy may be important because one may want a liquid to either be attracted or to adhere to the surface or one may want it be repelled by the surface.  The wetting of the surface by an adhesive or by a coating material will be affected by the surface energy.  Or, the measurement of the surface energy may just be used as a good indicator of having achieved a desired surface chemistry upon processing a material or having given it a surface treatment.  The measurement of the contact angle is often a good test of the cleanliness of a surface as well since the contaminated surface may wet more or less easily than the clean surface does.

Liquid droplets are applied to the surface using a syringe.  The small droplet is observed using a microscope aligned for sideways observation of the droplet on the surface of interest.  The image of the droplet is then analyzed by computer software from points marked along the droplet-air interface to calculate the contact angle at the droplet-surface interface.  These measurements are made by Dr. Kevin Wepasnick.

Example of a Contact Angle Measurement

These images illustrate the contact angle measurement of both water droplets and a plasticizer. The process involves placing a liquid on a desired surface in order to examine how the substance interacts with the material, such as treated metal. Figure 1, an image of water, demonstrates a high contact angle caused by the surface’s hydrophobic properties, whereas Figure 2, an image of the plasticizer droplet, shows stronger interaction with the surface or a greater ability to wet the surface. This is seen in its low contact angle and shallow profile. The surface is said to have a lower surface energy with respect to the plasticizer than with respect to water.

The next two images were taken after the contact angle measurement had been completed. The diagonal green lines are tangent to the three phase contact points, where the liquid, surface, and air meet on the edge of the drop, while the horizontal line shows the surface plane of the solid material. Both a circle fitting method and ellipse fitting method are displayed, which connect points along the surface of the water droplet before making calculations.

water-raw

Fig. 1.  A water droplet on the surface is seen to have a high contact angle, which indicates a hydrophobic surface.

santicizer-raw

Fig. 2.  A droplet of plasticizer on the same surface has a much lower contact angle indicating a readiness to wet this surface.

water-analyzed

Fig. 3.  The water droplet is shown here as analyzed to measure the contact angle.

santicizer-analyzed

Fig. 4.  The plasticizer droplet is shown here with the analysis used to measure the contact angle.